Soil and Groundwater Contamination Survey and Countermeasure Technologies



Decomposition of Gaseous Chlorinated Compounds under Ultraviolet Ray
 
Category of Tchnology Treatment Treatment
Media Soil Gas, Others (Off-gas from the stripper)
Contaminants
  • Volatile Chlorinated Organic Compounds (TCE, PCE, etc)
Applied (Demonstrated) Substances Trichloroethylene
Scope Concentration Range Gas containing up to 1000 ppmv of trichloroethylene was successfully treated in a test.
Hydrogeological Conditions
-
-
Chemical Soil Properties  
Other Remarks  
Technology Description Classification Decomposition
Status
  • Under Demonstration
Outline of Technology The gas extracted from underground soil, or treated by aeration, is passed through a filter and led to a 2-stage reaction tank, where it is exposed to the radiation of ultraviolet ray to decompose trichloroethylene, etc., in the air.  The waste gas is passed through the absorption tower, filled with marbles wet by water, which absorbs the compounds formed as a result of the decomposition.
Required Pre- and Post-treatment This is to treat the gas extracted from underground soil, or the waste gas after being treated by aeration.   It is necessary to treat the waste water from the absorption tower because the organic matters formed are absorbed in the tower (activated sludge method).
Enhance Effectiveness through Combination  
Case History The decomposition rate was higher than 96% in a test in which the gas containing 1500 ppmv of trichloroethylene was treated at a speed of 0.4m3 per minute.  Although the rate decreased when the concentrations at the entrance fell, or gas flow increased, the concentrations of trichloroethylene were low at below 1 ppmv at the exit of the second stage reaction tank.  Organic matters formed as a result of the decomposition were removed without problem, by being absorbed by marbles at the space velocity of 450hr-1.
Application Examples  
Limitations  
Properties of Treated Soil
-
Schematic Flow Process
Applicability In Situ Applicability Possible
Ground Structures
-
Required Excavation  
Groundwater Extraction  
Required Space  
Operational Time  
Installation Time  
Maintenance and Control Requirements  
Additional Remarks  
Secondary Impacts to Environment Secondary Treatment Required? Effluent Water Treatment   
Effects on Living Environment Noise
Additives
  • Water
  • Others (Ultraviolet rays)
  • Possibility of Contaminant Spreading None
    Secondary By-products VOCs form as a result of the decomposition, but they are removed by being processed with marbles.  It has been confirmed that this process is free of mutagenicity.
    (July 2002)
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