Soil and Groundwater Contamination Survey and Countermeasure Technologies



The Catalytic Oxidation of Volatile Chlorinated Organic Compounds
 
Category of Tchnology Treatment Emission Control
Media Soil Gas, Others (Off-gas from the Stripper)
Contaminants
  • Volatile Chlorinated Organic Compounds (TCE, PCE, etc)
Applied (Demonstrated) Substances Trichloroethylene (TCE)
Scope Concentration Range In the case of the concentration of influent is over 2,500ppmv, it will be fed with fresh air to dilute for avoiding damage for catalyst reactor and heat exchanger.
Hydrogeological Conditions
-
-
Chemical Soil Properties  
Other Remarks  
Technology Description Classification Decomposition
Status
  • Under Demonstration
  • Soil and Groundwater Countermeasure Test Study (Performed 1993)
Outline of Technology The soil vapor contaminated with VOCs is induced to gas-liquid separator to remove mist and sand particles. The vapor is induced to heat exchanger to pre-heat by exhaust gas. After heated by electric heater, the soil vapor is led to reactor to decompose VOCs. The reactor is filled by honeycomb structure Ti-Si complex catalyst. The gas generated by the oxidation reaction is exhausted after washed and neutralized by alkali scrubber to remove hydrogen chloride.
Required Pre- and Post-treatment Soil vapor extraction system or pumping aeration system is necessary as pre-treatment stage. If the harmful components generate contingently, the exhaust treatment device is necessary.
Enhance Effectiveness through Combination  
Case History In case of inlet temperature of vapor is set to 350°C, it is obtained 99.5% of removal ratio as VOCs, even the space velocity (SV) is set to 3000 1/h.
In this case, the influent concentration 1000ppmv, the effluent concentration is 3ppmv.
Application Examples  
Limitations  
Properties of Treated Soil
-
Schematic Flow Process
Applicability In Situ Applicability Possible
Ground Structures
-
Required Excavation  
Groundwater Extraction  
Required Space 8m2 of floor space are necessary to install this system.
Operational Time  
Installation Time  
Maintenance and Control Requirements Monitoring items; flow rate of soil vapor, concentration of influent and effluent gas, conditioning of solution in regard to alkali scrubber.
Additional Remarks  
Secondary Impacts to Environment Secondary Treatment Required? Off-gas Treatment
Effects on Living Environment  
Additives Air
Possibility of Contaminant Spreading There is no emission of contaminants, if treatment of exhaust gas is performed adequately.
Secondary By-products For reaction in high temperature, there is a possibility generating harmful components.
(July 2002)
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