Soil and Groundwater Contamination Survey and Countermeasure Technologies



Chlorination
 
Category of Tchnology Treatment Treatment for Excavated Soil
Media Soil
Contaminants
  • Heavy Metal (Cd, Pb, As, Hg, Se, etc) 
Applied (Demonstrated) Substances Cu, Pb, Zn, Cd
Scope Concentration Range  
Hydrogeological Conditions
-
-
Chemical Soil Properties  
Other Remarks  
Technology Description Classification Separation
Status
  • Under Demonstration
  • Soil and Groundwater Countermeasure Test Study (Performed 1995)
Outline of Technology Contaminated soil and calcium chloride mixture is heated to 800 to 1000°C to remove heavy metals as metal chloride whose boiling temperature is low.  Exhaust gas and effluent are cleaned.
Required Pre- and Post-treatment Exhaust gas treatment
Enhance Effectiveness through Combination Treated volume is desirably reduced with previous soil washing.
Case History Pb, Cd, Zn contents are considerably reduced by 800 to 1000°C heating in 30 to 60 minutes.  Cu, however, don’t reduce in this condition.  Soil environmental standard is cleared in all element. 
Application Examples Long history as a heavy metal recovery technology for minerals and hazardous waste.
Limitations  
Properties of Treated Soil Possibility of Change in Properties 
Schematic Flow Process
Applicability In Situ Applicability Not Possible
Ground Structures
-
Required Excavation Excavated soil is treated (To be applied to the excavated soil)
Groundwater Extraction None
Required Space
-
Operational Time  
Installation Time  
Maintenance and Control Requirements  
Additional Remarks  
Secondary Impacts to Environment Secondary Treatment Required?
  • Effluent Water Treatment   
  • Off-gas Treatment
  • Effects on Living Environment Noise
    Additives Others (Calcium chloride)
    Possibility of Contaminant Spreading None
    Secondary By-products It may be needed to check the possibility of genertation of unintentional by-products depending upon the co-existing components in the contaminated soil.
    (July 2002)
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