Soil and Groundwater Contamination Survey and Countermeasure Technologies



Thermal Treatment of Heavy Metal Contaminated Soil
 
Category of Tchnology Treatment Treatment of Excavated Soil
Media Soil
Contaminants
  • Heavy Metal (Cd, Pb, As, Hg, Se, etc)
Applied (Demonstrated) Substances Pb, Zn, Hg
Scope Concentration Range  
Hydrogeological Conditions
-
-
Chemical Soil Properties Difficult for low melting point soil
Other Remarks Applicable for complex contamination with organic materials
Technology Description Classification Separation
Status
  • Under Demonstration
  • Soil and Groundwater Countermeasure Test Study (Performed 1993)
Outline of Technology Volatile heavy metals are removed from contaminated soil by vaporization in a rotary kiln, which is heated with fuel and air at the temperature of 1000 to 1100°C.  Non volatile heavy metals also change to insoluble oxide by heating.  Treated soil is cooled rapidly or gradually.  Exhaust gas is cleaned by alkali solution and electrostatic precipitator. 
Required Pre- and Post-treatment Heavy metals in exhaust gas should be removed and treated appropriately. 
Enhance Effectiveness through Combination  
Case History A contaminated soil with high concentration of Zn, Hg, and soluble Pb is treated.  Rapidly cooled soil has met the soil environmental quality standard through elution test in pH 7.
Application Examples  
Limitations Properties of Treated Soil are considerably changed.  Physical properties don’t meet the construction material standard, though it meets soil environmental quality standard.  Treated soil can only goes to landfill.
Properties of Treated Soil Possibility of Change in Properties
Schematic Flow Process
Thermal Treatment System of Contaminated Soil
Applicability In Situ Applicability Not Possible
Ground Structures
-
Required Excavation Excavated soil is treated (To be applied to excavated soil)
Groundwater Extraction  
Required Space
-
Operational Time  
Installation Time  
Maintenance and Control Requirements  
Additional Remarks  
Secondary Impacts to Environment Secondary Treatment Required?
  • Effluent Water Treatment   
  • Off-gas Treatment
  • Effects on Living Environment Noise
    Additives
  • Air
  • Others (Fuel)
  • Possibility of Contaminant Spreading None
    Secondary By-products Depends on coexisting materials
    (July 2002)
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