Soil and Groundwater Contamination Survey and Countermeasure Technologies



Carbon Adsorption/Electromagnetic Desorption/Mass Spectroscopy  (CA/ED/MS)
 
Category of Tchnology Survey In Situ Extraction Technology
Media Soil Gas
Contaminants
  • Volatile Chlorinated Organic Compounds (TCE, PCE, etc)
  • Volatile Hydrocarbon (Benzene, etc)
Applied (Demonstrated) Substances  Volatile Chlorinated Organic Compounds
Scope Concentration Range  equivalent to 1 ppbv in concentration
Hydrogeological Conditions
  • Unsaturated
  • Permeable Layer
Chemical Soil Properties  
Other Remarks  Soil gas distribution in soil is comparatively expressed by ion-counts obtained from mass spectroscopic analysis
Technology Description Classification  
Status
  • Fully Commercialized
  • Soil and Groundwater Countermeasure Test Study (Performed 1993)
Outline of Technology Activated carbon is glued on the end of ferro-magneticwires inserted into bore hole of approximately 30cm in depth for 2 to 3 weeks.  Wires in the glass tube exposed in soil gas are retrieved and the soil gas desorped by heating is analyzed by mass spectroscopy.
Required Pre- and Post-treatment  
Enhance Effectiveness through Combination Linear survey method, to which the soil-gas method is applied, for surveying the plume containing contaminated groundwater and for searching the contaminant source.
Case History Because the positioning of collectors in boreholes does not require long time, it may averagely be possible to finish the positioning within a day or two at sites.  For the adsorption and analysis, it will take much longer time.  It is possible to detect pollutants 50-100m apart from the origin of contamination in the soil gas investigation.
Application Examples It can be used in wider range of soil gas concentration in detection survey of contamination source or in industrial property survey.
Limitations Longer time required in adsorption period and in mass analysis to obtain ion count distribution.
Properties of Treated Soil
-
Schematic Flow Process
 Gas Collector Setup for CA/ED/MS
Applicability In Situ Applicability Possible
Ground Structures Applicable even if Ground Structures are Present * 
Required Excavation  Gas collectors to be put in bore holes of in 15cmφ x 30cm depth.
Groundwater Extraction  None
Required Space  1-2 m2
Operational Time
-
Installation Time  Gas collectors to be placed for 2 to 3 weeks before MS analysis.
Maintenance and Control Requirements
-
Additional Remarks  * Drill cutter is necessary for concrete floor.
Secondary Impacts to Environment Secondary Treatment Required?
-
Effects on Living Environment  
Additives
-
Possibility of Contaminant Spreading None
Secondary By-products
-
(July 2002)
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